Option 1 b.5

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Information about Option 1 b.5

Published on March 9, 2014

Author: brownm7

Source: slideshare.net

Option 1B 1

1B.5 The Ozone Layer 2

Ozone O3  It is a pale blue gas, which condenses to a deep blue liquid.  It is found in the upper atmosphere (stratosphere) where it absorbs the harmful UV radiation from the Sun, which can cause skin cancer.  It’s also possible to get a sharp smell of ozone near photocopiers, where electricity passes through the air.  In the lower atmosphere it can be detrimental to health aggravating asthma and bronchitis. 3

Formation of Ozone Ozone, O3  O3 is formed naturally in the stratosphere by the reaction between an oxygen atom and an oxygen molecule.  The oxygen atoms are formed when UV light breaks an oxygen molecule. O2 O + O This is an example of photodissociation 4

Formation of Ozone Ozone, O3  Oxygen atoms are very reactive as each has an unpaired electron and are called free radicals. As soon as they are formed, they react with oxygen molecules to form ozone. O + O2 O3  When O3 absorbs UV light photodissociation of the ozone occurs. O3 O + O2 5

Formation of Ozone Ozone, O3  Some of the oxygen atoms destroy ozone molecules forming oxygen molecules, which are then broken down by UV light to form more oxygen atoms, which lead to the production of more ozone. O + O3 2O2  So ozone is being made and destroyed all the time! 6

 It was thought that there was a constant amount of ozone in the atmosphere, but in 1984, scientists discovered that the concentration over the Antarctic was decreased. This is often referred to as the ‘hole’. There is also a ‘hole’ in the ozone layer above the Arctic. It occurs there because of the unique climate there. 7

Chlorofluorocarbons  Thomas Midgley developed Freons and Tetra Ethyl Lead.  CFC’s (chlorofluorocarbons) are a family of compounds that contain the elements chlorine, fluorine and carbon only. Trichlorofluoromethane (Freon-11) 8

Properties CFC’s      Very unreactive and stable in the lower atmosphere. Long residence time/lifetime ~100 years Low toxicity Low boiling points Low flammability Uses of CFC’s  As refrigerants/coolants in fridges and freezers.  In air conditioners  In aerosol propellants 9

 However when they are transported into the upper atmosphere/ stratosphere they become very reactive as they are broken down by UV radiation.  The chlorine atoms released then attack ozone.  One single chlorine atom can destroy tens of thousands of ozone molecules. 10

‘Ozone Hole’ Ozone hole increased 50% from 1975 - 1985 11

How CFC’s give rise to ozone depletion  They are broken down by UV light in the upper atmosphere to form chlorine radicals. CCl3F CCl2F + Cl  These Cl attack ozone: O3 + Cl ClO + O2  A chain reaction is set up.  ClO + O Cl + O2 12

Role of NO in destroying ozone  Nitrogen monoxide: NO can also destroy ozone. NO + O3 O2 + NO2  But chlorine radicals Cl are the main offenders. 13

Role of Methane in absorbing  Cl Although methane is a greenhouse gas it helps slow down the rate of ozone depletion by removing Cl CH4 + Cl CH 3 + HCl 14

CFC substitutes HCFC’s (hydrochlorofluorocarbons) are broken down by radicals naturally in the lower atmosphere and don’t reach the upper atmosphere e.g. CHCLF2 (chlorodifluoromethane) which is a propellant used in ‘ozone friendly’ aerosols. BUT 1. They do destroy some ozone. 2. They are greenhouse gases and thus contribute to global warming. 3. A lot of research is going into HFC’s (hydrofluorocarbons) 15

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