Kcpk presentation

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Information about Kcpk presentation
Technology

Published on March 26, 2014

Author: PolKnops

Source: slideshare.net

Description

A presentation (in Dutch) held at the KCPK meeting.
The meeting was about Energy Reduction and CO2.

Reduc&e'Energie'&'CO2'  Kenniscentrum+Papier+en+Karton+  www.kcpk.nl+  Themamiddag+“Reductie+Energie+&+CO2”+  Datum:+ 25+maart+2014+12.30+–+16.00+  Lezing:+CO2+Capture+&+Energy+Reactor+  Locatie:+Facility+point,+Meander+251,+Arnhem+  Doelgroep+proces+technologen+en+energie+coordinatoren+ 1+

CO2'Energy'Reactor' Productie*mét*CO2* Ir. Pol Knops: Innovation Concepts KU Leuven Dr. Rafael Santos: KU Leuven 2+

CO2'Energy'Reactor' Presentatie*  Doel+  Methode+  Resultaten+  Planning+  Vragen+ 3+

Doelen'  1.+PCC+analogie+&+Silica+uit+Olivijn+  2.+PCC+productie+uit+residue+materiaal+  Opwaarderen+residu+materiaal+  Grondstof:+CO2*(CO2+ReWuse)+ .+ Géén+typisch+CO2+project++ .+ (focus*eind*producten,*valorisatie*€€)*  Bijproduct+warmte+(170°C)+ 4+

Twee'processen'  1.+ Olivijn* *  .+ Mg2SiO4+++2+CO2+=>+2+MgCO3+++SiO2+ .+ + + + + + Warmte* + .+ + + + + MgCO3:+Alternatief+PCC+ + .+ + + + + SiO2:+Silica+(papier)+  2.++ Residu*materialen*(staalslakken)* * + .+ Ca(OH)2+++CO2+=>+CaCO3+++H2O+ .+ + + + + + Warmte+ + .+ + + + + Aragoniet+(PCC)+ 5+

Werking'  CO2$energy$reactor$  Reactie:+  Hogere+temperatuur+  Hogere+druk+  Verblijftijd+  Exotherm:+ Warmte+aftappen+ 6+

Historie:'Zuiveringsslib' 7+

Test'apparaat' 8+

Eind'producten' Sample:(U3' 9+

Resultaten' 10+

Opwerken'staalslakken' 11+

Aragonite(Synthesis(   Aim:+promote+aragonite+formation+over+calcite+to+produce+new+materials+ and+potentially+intensify+carbonation+reaction.+   Objectives:+use+combination+of+recognized+process+parameters+to+promote+ aragonite+(ultrasound+and+MgCl2),+assess+purity+and+properties+of+material.+   Parameters:+temperature,+Mg:Ca,+CO2+flow+rate,+US+amplitude/cycle,+ Solids+conc.,+reactor+volume,+additive+recycle.+   Resources:+Master’s+thesis+student+(P.+Ceulemans,+2010W2011),+Bachelor+ thesis+student+(J.+Thijs,+2014).+ 12+

Aragoniet(vorming( 70oC+ 55oC+ Ultrasound+mixing+ Mechanical+mixing+ Effect+ultrasoon+op+precipitated+calcium+carbonate+(PCC)++ 13+

Aragoniet(vorming( 40oC+ 30oC+ Ultrasound+mixing+ Mechanical+mixing+ 14+ Effect+ultrasoon+op+precipitated+calcium+carbonate+(PCC)++

Aragoniet(vorming( Resultaten:*   Ultrasound+&+Mg2++bevordert+Aragonite+synthese+door+carbonisatie+   Zuiver+(>98%)+aragoniet+neerslag+bij+24+oC+(optimale+process+condities)+   Invloed+process+parameters+op+product+kwaliteit+onderzocht+ (optimalisatie)+   Nieuw+Aragoniet+(CaCO3)+kristal+morfologie+(hubbard+squashWlike)+ geproduceerd+bij+lage+temperaturen.+   Batch+proces+getest+als+scale+up+route+for+productie+Puur+Aragoniet+ poeder+ 15+

 Process+ontwikkeld+om+staalslakken+to+valoriseren:+   Carbonisatie+van+CaWionen+naar+PCC*   Hydrothermal+conversie+van+slakken+naar+zeolieten+  Selectieve+uitloging+is+bepalend+  Verscheidene+publicaties+  Komend+jaar+(Toronto):+PCC+in+Paper+&+Coatings+ Valoriseren(van(staalslakken( Contact:* Rafael+Santos,+Postdoctoral+Fellow+ KU+Leuven,+Dept.+Chemical+Engineering+ rafael.santos@cit.kuleuven.be+ 16+

Olivijn'  CO2+vastlegging+  Productie:++ MagnesiumWCarbonaat+ .+ + + Silica+  Warmte+  Full*scale:*  100+m3/hr:+280+kton+Olivijn+ .+ + 160+kton+CO2+ .+ + 320+kton+Magnesiet+(PCC+alternatief)+ .+ + 180+kton+Silica+ .+ + 13*Mwatt(th)* ++ 17+

Planning'  2009+ Start,+patent,+literatuur+  2011++ Batch+autoclaaf+  2012++ Samenwerking+KU+Leuven+  2013++ Research+consortium:+ .+ + Sibelco,+Steel+producer,+ISPT,+I.C.+ .+ + University+Louvain+&+Lorraine+  2014++ Continu'autoclaaf' .' ' Uitbreiding'consortium::'CO2,'eind'producten' .' ' ' '  2017'' Einde'continu'autoclaaf'testen'  2018++ Beslissing'full'scale+ 18+

Vragen'?' Take*home*message:*  CO2+als+grondstof:+CCUS+ Carbon+Capture+Utilisation+Storage+  Betalende+eind+producten+  “BijWproduct”+warmte+  Vragen:*Partners*voor*product*ontwikkeling* Pol Knops www.innovationconcepts.eu knops@innovationconcepts.eu Tel: 06-51304842 19+ Rafael Santos, Postdoctoral Fellow KU Leuven, Dept. Chemical Engineering rafael.santos@cit.kuleuven.be

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