chap16

50 %
50 %
Information about chap16
Entertainment

Published on February 25, 2008

Author: Bruno

Source: authorstream.com

ALDEHYDES AND KETONES I. Nucleophilic Addition to Carbonyl:  ALDEHYDES AND KETONES I. Nucleophilic Addition to Carbonyl Chapter 16 Reading Assignment:  Reading Assignment SKIP: Section 16.8 SKIP: Section 16.19 I will be covering the remaining sections. Problem Assignment:  Problem Assignment In-Text Problems 16.1 and 2 3 (except for d) 5 - 10 12 - 18 21 - 25 End-of-Chapter 1 3 - 5 7 (all but b) 8 b, c, d 10 12 Nomenclature of ketones:  Nomenclature of ketones 2,5-dimethyl-3-hexanone Slide5:  2,5-dimethyl-5-hexen-3-one Slide6:  2,6-dimethyl-1,4-cyclohexanedione Slide7:  5,6-dimethyl-5,7-octadien-3-one Slide8:  5-bromo-2-methylacetophenone Some Common Names of ketones:  Some Common Names of ketones Slide10:  3,4-dimethylpentanal Nomenclature of aldehydes Slide11:  3,4-dimethyl-3,5-hexadienal Slide12:  4,5-dimethyl-2,4-heptadienedial Slide13:  3,4-dibromobenzaldehyde Some common names of aldehydes:  Some common names of aldehydes Sect. 16.5: Nucleophilic Addition to Carbonyl -- in base:  Sect. 16.5: Nucleophilic Addition to Carbonyl -- in base Nucleophilic Addition to Carbonyl -- in Acid:  Nucleophilic Addition to Carbonyl -- in Acid Sect. 16.6: Addition of Cyanide:  Sect. 16.6: Addition of Cyanide Sect. 16.7: Addition of Organometallic Reagents:  Sect. 16.7: Addition of Organometallic Reagents Synthesis of Alcohols using Grignard reagents - revisited:  Synthesis of Alcohols using Grignard reagents - revisited ketone tertiary alcohol Slide20:  Synthesis of Alcohols The type of alcohol depends on whether you use formaledhyde, another aldehyde, or a ketone. formaldehyde other aldehydes ketones primary alcohol tertiary alcohol secondary alcohol RMgX + RMgX + RMgX + Reaction of RMgBr with aldehydes and ketones yields alcohols Sect. 16.9: Addition of Water:  Sect. 16.9: Addition of Water Sect. 16.10: Addition of Alcohols:  Sect. 16.10: Addition of Alcohols Formation of Acetals:  Formation of Acetals A popular acetal!:  A popular acetal! Sect. 16.11: Protective groups:  Sect. 16.11: Protective groups Sect. 16.12: Addition-Elimination: The Formation of Imines:  Sect. 16.12: Addition-Elimination: The Formation of Imines Formation of Simple Imines:  Formation of Simple Imines Formation of Oximes:  Formation of Oximes hydroxylamine an oxime Formation of Hydrazones:  Formation of Hydrazones a hydrazine 2,4-Dinitrophenylhydrazones:  2,4-Dinitrophenylhydrazones 2,4-dinitrophenylhydrazine Formation of Semicarbazones:  Formation of Semicarbazones semicarbazide Addition-Elimination: The Formation of Imines:  Addition-Elimination: The Formation of Imines Sect. 16.13: Formation of Enamines:  Sect. 16.13: Formation of Enamines Enamine Formation (Part One):  Enamine Formation (Part One) Enamine Formation (Part Two):  Enamine Formation (Part Two) Nucleophilic Character of Enamines:  Nucleophilic Character of Enamines Reactions of Enamines as Nucleophiles:  Reactions of Enamines as Nucleophiles Hydrolysis of Iminium Salts (Part One):  Hydrolysis of Iminium Salts (Part One) Hydrolysis of Iminium Salts (Part Two):  Hydrolysis of Iminium Salts (Part Two) Enamine Reactions -- Summary:  Enamine Reactions -- Summary Slide41:  Gilbert Stork, developed enamine chemistry and also did a total synthesis of Quinine C & E News, 26 Feb, 2007 Slide42:  Quinine has four stereocenters! Source of picture: Michigan State University, Department of Chemistry http://www.chemistry.msu.edu/Portraits/PortraitsHH_collection.shtml Slide43:  William Doering (left) and R.B. Woodward, Harvard, synthesized precursor to quinine, 1944. Notice the cigarette! Woodward won the Nobel Prize in 1965. Slide44:  Woodward (left) and Doering discussing the synthesis of quinine. Slide45:  K. B. Wiberg, Yale University, Lampman’s Ph.D. adviser. Wiberg was a Ph.D. student of Doering. Lampman chemical genealogy:  Lampman chemical genealogy Slide47:  Gabrielle Fallopio Slide48:  Justus von Liebig Slide49:  August Wilhelm von Hofmann Lampman chemical genealogy:  Lampman chemical genealogy Sect. 16.14: The Wittig Reaction:  Sect. 16.14: The Wittig Reaction Ylide:  Ylide A compound or intermediate with both a positive and a negative formal charge on adjacent atoms. Resonance in Ylides:  Resonance in Ylides Mechanism:  Mechanism Preparation of the Ylide:  Preparation of the Ylide Slide56:  George Wittig, nobel prize, 1979 Carbohydrates Sections 16.15 - 16.18:  Carbohydrates Sections 16.15 - 16.18 Emil Fischer :  Emil Fischer Source: Michigan State University, Department of Chemistry http://www.chemistry.msu.edu/Portraits/PortraitsHH_collection.shtml Norman Haworth:  Norman Haworth Source: Michigan State University, Department of Chemistry http://www.chemistry.msu.edu/Portraits/PortraitsHH_collection.shtml Sect. 16.15: Cyclization of Monosaccharides:  Sect. 16.15: Cyclization of Monosaccharides Slide61:  Alpha D(+) glucose Slide62:  Beta D(+) glucose Mutarotation of Glucose:  Mutarotation of Glucose b-1,4-Glycosidic Linkage:  b-1,4-Glycosidic Linkage a-1,4-Glycosidic Linkage:  a-1,4-Glycosidic Linkage Sucrose:  Sucrose

Add a comment

Related presentations

Related pages

chap16.ga

Though no experience is required to participate in the Coal Heritage Archaeology Project, please list any museum, archives, or archaeological training or ...
Read more

Chap16 - scribd.com

Chap16 - Download as PDF File (.pdf), Text File (.txt) or read online.
Read more

CHAP16 - PDF Books Download

CHAP16 PDF Books EPUB Free Chap16 PDF Books Pin on Pinterest Tweet CHAP16 - Are you searching for Chap16 Books? Now, you will be happy that at this time ...
Read more

Chap16 - scribd.com

1Chapter 16: Slug Tests As an alternative to aquifer pump tests, slug tests can be preformed to determine the hydraulic conductivityof the format...
Read more

CHAP16 - Download PDF Books Epub Free

CHAP16 Download PDF Books Epub Free Chap16 PDF reddit share Share on Twitter facebook CHAP16 - Are you searching for Chap16 Books? Now, you will be happy ...
Read more

chap16 - pt.scribd.com

chap16 - Download as Powerpoint Presentation (.ppt), PDF File (.pdf), Text File (.txt) or view presentation slides online. ib
Read more

chap16 - MYP Mathematics

C h a p t e r 1 6 Tr i g o n o m e t r i c r a t i o s a n d t h e i r a p p l i c a t i o n s 771 Non–right-angled triangles — the sine rule
Read more

Chapter 16: Inheritance

Chapter 16 Inheritance 16.1 Inheritance. The language feature most often associated with object-oriented programming is inheritance. Inheritance is the ...
Read more

chap16 - researchgate.net

16 BASIC PROPERTIES OF CONVEX POLYTOPES Martin Henk, Ji_irgen Richter-Gebert, and Günter M. Ziegler INTRODUCTION polytopes are have since The of their by ...
Read more

RESEARCH METHODS EXPERIMENTAL DESIGN A set of notes ...

RESEARCH METHODS & EXPERIMENTAL DESIGN A set of notes suitable for seminar use by Robin Beaumont Last updated: Sunday, 26 July 2009 e-mail: robin@ ...
Read more